Are photocopies and laser prints suitable for long-term preservation?

Photocopying and laser printing have become commonplace, but if the information being copied or printed is for long-term retention, issues of image stability need to be considered.

This advice explains the technologies and their suitability for creating records for long-term retention.

Photocopying processes

Xerography

Xerography, the most common photocopying process, uses the basic principles of static electricity to create an image on a sensitised surface and then transfer it to paper, as described below.

  1. A strong electrical charge is applied to the surface of a photosensitive plate.
  2. The image is projected onto the sensitised surface resulting in a pattern of surface charge called the latent electrostatic image. 
  3. Toner is electrostatically attracted to the latent image, resulting in a visible image of electrostatically held toner particles. 
  4. A sheet of paper is brought into contact with the plate surface. An appropriate charge applied to the back side of the paper attracts the toner image to it. The paper leaves the plate with the toner clinging to it electrostatically. 
  5. Dry toners are fused to the page by heat and pressure. Liquid toners are fixed by air-drying or heating. 

Laser printing

The laser printing process is very similar to the xerographic photocopying process. The major difference is that the exposure step for laser printers employs a laser beam to draw the image onto the sensitised surface to form the latent electrostatic image.

Single-colour photocopying and laser printing

Both single-colour photocopying and single-colour laser printing employ the same technology as dry toner black photocopying and laser printing.

Full-colour photocopying

Full-colour photocopying uses the same principles as the equivalent dry toner single-colour xerography technology except that the process is repeated once for each colour – yellow, magenta and cyan, and then black. That is, each colour is separately laid onto the paper. 

Toners and their effect on image permanence

Dry toners

A typical dry toner is predominantly composed of a heat-sensitive polymer, acrylic or styrene, or both. The next major ingredient is a pigment such as carbon black. Carriers are an active ingredient in a toner. They are used to generate a charge on the toner particles. The carrier is typically an iron or steel powder, which may be coated with resin. The presence of carriers in the image formed on paper may adversely affect the stability and longevity of documents, particularly those created by the liquid process. Dry toners mostly remain on the surface with little penetration of the paper fibres, therefore the effect of carriers is lessened.

Some toners do not contain carriers. These toners, known as single-component toners, employ a magnetised roller to charge the toner particles.

Liquid toners

Liquid toners are composed of a suspension of pigmented or dyed resin particles in an insulating liquid. The liquid process involves washing or spraying the electrostatic image with this dispersion.

Liquid toner particles are significantly smaller than dry toner particles and usually contain acrylic resin combined with carbon black.

Images formed from liquid toners penetrate and colour the paper fibres, unlike dry toners, which adhere to the paper surface. Liquid toner images cannot easily be removed from the surface of the paper.
Liquid toner has some limitations. Even though the liquid carrier is fast drying, it does not evaporate instantly. Hence liquid-based systems work at about half the speed of the equivalent dry toner system. Images formed from the liquid process are also prone to fading.

Colour toners

Colour toners are commonly based on organic dyes, which are subject to fading and known to change colour. Xerographed documents that are to be retained long term should be made using dry toners containing pigments of known stability and on archival quality papers.

A recent study showed that various colour toners perform differently under identical irradiation with ultraviolet (UV) light sources. Colour toners that had pigment impregnated within a polyester resin showed better fusion with the page and the printed images were less subject to fading. This is because polyester is a good absorber of UV light. This theory is supported by the finding that photographs placed in polyester sleeves are less subject to fading.

Degradation of toner materials

Choice of toner depends largely on its particular characteristics and suitability for different applications. When choosing a toner for the creation of long-term records, degradation of the toner should be considered. Toner materials may degrade because of the following factors:

  • heat
  • oxidation
  • chemical attack, such as air pollution
  • physico-chemical changes such as separation of toner components
  • physical stresses caused by changes in environmental conditions.

Carbon black, used in most black toner formulations, is a light blocker and absorber, which helps prevent light-related degradation reactions.

Adhesion of toner to paper

The physical durability of a xerographed copy depends primarily on how well the toner adheres to the paper. Time, temperature and pressure appear to be the most important factors, but adhesion may also be affected by the surface finish and porosity of the paper. It is more difficult for dry toners to penetrate coated papers and papers with small pore sizes. Moisture content of the paper can be critical for the toner-to-paper transfer process and may also affect the fixing process.

Full-colour images are thicker than black toner images because they are composed of four layers of toner. Consequently, they do not fully adhere to the paper and are more prone to flaking during flexing or folding.  

Practical recommendations

The durability of photocopied and laser-printed documents depends largely on the quality of the paper used, as well as the degree to which the paper and toner adhere after processing.

  • Toners composed of stable resin materials and a stable pigment such as carbon black are capable of strong bonding to the paper surface. Copies using these toners and printed onto permanent or archival quality paper can be considered permanent and suitable for long-term storage.
  • Do not stack or weight dry toner images at high temperatures. Do not place them in direct contact with PVC as this makes the toner sticky and capable of transferring to adjacent surfaces (polyester or polypropylene film is safe).
  • Copy machines should be maintained regularly by qualified technicians to ensure that they are operating at the correct temperature to fuse the toner. 
  • There is sufficient evidence that colour xerographed images do not last as long as black and white copies. Most international archival institutions do not recommend the permanent or long-term storage of colour photocopied or laser-printed material. 
  • Maximise the life of colour photocopies and laser-printed copies by storing them in the correct environment and minimising exposure to light.
  • Do not flex or fold full-colour dry toner copies as the print layer is thicker and may crack under deformation.
  • Store colour liquid-toner copies away from all light sources to reduce fading effects.

Further advice

Please contact the Agency Service Centre if you need further advice on photocopied or laser-printed documents.

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